Historical Articles
THE MONTHLY REVIEW
American Electroplaters Society
Publication and Editorial Office
3040 Diversy Ave., Chicago
Vol. XIV JANUARY, 1927 No. 1
EDITORIAL
Is the art of electroplating becoming less an art, and a mere commercial process?
It appears to be a fact with respect to certain branches of the industry. Some
one has said, The love of work is a natural instinct, and to deprive a
man of the opportunity to work is a crime. But it is; a greater crime to prevent
men from producing something worth while. To make them lose sight of art, skill
or quality by insisting upon poor workmanship is degrading and discouraging.
Men of; character devote their lives to the work they love. They take great
pride in the work they produce if it is good. Every accomplishment spurs them
on to greater effort.
How it must hurt the particular individuals
who take pride in the work they love to have some person tell them anything
will doproduction is what we want. How discouraging when one
must lose sight of all art, skill, beauty and craftsmanship which took years
to acquire in order to earn a livelihood. We often wonder why there are not
more men than there are who lose interest in their particular profession or
3 occupation when they are not given the opportunity to use that which they
possess to produce the best or highest in their particular line.
Those words are applicable to many
of the electro-plating positions on this continent today. Is the answerCompetition?
No, the answer isThe electroplater by reason of the broadening influence
of the American Electro-Platers Society will meet the situation with the
spirit of progress and unite with the manufacturers in making the plated products
of 1927 cheaper, but equally as durably finished as before the great war. Then
in the future years when the rush and scrimmage is over and we have more time
to think, experiment and devise we can put art into every article we produce.
Associate Editor W. S. Barrows,
Past Pres. A.E.S.
Small brass pieces such as screws,
nuts and many others that require copper plating either to remain copper or
for other black finishes.
If one tries to copper-plate them
in a brass mesh plating -basket direct in the acid copper solution after the
usual cleaning, one would not get very far. I have tried it and have had very
little success. The parts that do not touch each other might receive a thin
coating of copper, but when a large amount is put in the basket they cannot
help touching one another, and it will be a hard proposition to get them to
plate all over.
The best method I have found, and
it works quite successful, is to hang the basket with the articles in the nickel
tank first and give them a coating of nickel; leave them in until they are pretty
well covered with nickel, then take them out and rinse in water and hang in
acid copper solution. In about ten or fifteen minutes they will have a pretty
fair coat of copper and can be blackened for jap bronze or anything they might
call for. Of course, if there is a large quantity of this small work it would
pay to put in a mechanical cyanide copper solution. I am speaking only of the
shop that is not equipped with cyanide copper solution, either still or mechanical.
JERRY DeGRAZIA,
Foreman Plater, McGill Mfg. Co., Valparaiso, Ind.
George B. Hogaboom
To many the learning of the methods
for controlling the contents of electroplating solutions is considered a long,
difficult task. The methods of analyses as outlined in a beginners book
on chemistry are to a layman intricate and require more than ordinary skill
to even comprehend enough to be of assistance in a practical way in a plating
room. The symbols, equations, and chemical terms are viewed as a part of a strange,
incomprehensible language that can only be understood by those who have been
trained in the halls of learning where Latin, Greek, Egyptian hieroglyphics
and mathematics are taught. This was confirmed by some who, realizing the value
of chemistry as applied to electroplating, endeavored to study alone and without
the aid of a laboratory.
There were others that sought the
advice of trained chemists and were told that it would not be possible to gain
the goal ought unless competent instruction was had in the fundamental principles
of chemistry. It was difficult to find a suitable instructor. The chemist knew
as little about the practical side of electroplating as the plater did about
the principles of chemistry. Those who did attempt to teach planned a course
of study similar to what they had been taught. It was considered essential that
valence, the balancing of equations, the qualitative determination of unknown
solutions and such things, be thoroughly understood before the gravimetric or
volumetric analysis be studied. When it realized that it takes two years of
a college course to prepare student for quantitative analysis the task before
the plater was beset with many difficulties. Working all day as a plater, which
means at times being a machinist, an electrician, an artist, a production supervisor,
and above all, a good executive understanding how to teach and direct those
who at times are almost unteachable, consumes mental and physical energy. To
then give up the required hours of rest in evenings and Sundays to study the
reaction of some chemical combination that never would be of practical value
in a plating room, demands a sacrifice that many are not willing or even able
to make.
The need of training in chemistry
was clearly recognized. It was well known that with the advancements made in
the electro-deposition of metals that unless the plater became adept enough
to control the plating solutions by analysis that the chemist would replace
him and that he would become an ordinary production man. This was already being
done. Yesterday the manufacturer accepted plating troubles as unavoidable. Today
he is seeking men trained in chemistry to operate his plating room. Tomorrow
he will demand them. The knowledge that electroplating is no longer a mystery,
and that solutions and methods of operation are subject to definite scientific
laws is becoming more and more general. Soon it will be common knowledge, and
to many platers this will be a crisis. In all crises, however, a way of action
can always be found. As the development of electroplating was brought about
by the platers themselves, as members of the A . E. S., it is not strange that
a plater, rather than a chemist, should point out the way. This plater reasoned
that it is not necessary to be a mechanical or combustion engineer to operate
an automobile. A small kit of selected tools, a set of instructions and an instructor
to teach the use of the tools and how to operate the driving mechanism converts
a man into an automobile engineer. When troubles beyond comprehension develop,
the garage with its expert engineers is available. The same plan is applicable
to the electroplater. A small kit of tools glass wareand chemical reagentsa
set of instructions and an instructor to teach how to use the tools and how
to interpret the results will convert a plater into an electroplating chemist.
He need not know the fundamental principles of chemistry any more than a man
driving a car need to know about the fundamental principles of combustion engineering.
He need only to master the mechanics of the operations involved.
The Sizelove plan is to teach the
plater the mechanics of analyses of plating solutions. Volumetric methods for
analysis ;of all solutions used in the plating room have been worked out and
published in the March, 1926, Monthly Review. The necessary beakers, pipettes,
burettes and chemicals are easily obtainable.
The plan was tried out successfully
in a vocational school and the average attendance of plating room foremen for
a year was above 80 per cent, a direct contrast to the dwindling attendance
of classes where fundamental principles of chemistry was taught. The plater
students were given the necessary tools of glassware and reagents, a set of
instructions, and Mr. Sizelove was the instructor. Standard solutions for titration
were made and furnished the student; it was not necessary for him to master
the details of making and checking these, although this instruction was available.
In one term of 120 hours platers without any previous knowledge of chemistry
became proficient enough in the mechanics of analysis to control the solutions
in their plating room. As fast as the method for one solution was mastered it
was put into practice and the old saying, Practice makes perfect,
was never more true, and today these men control their solution, not by the
rule of thumb but by actual chemical analysis.
The teaching of chemistry to platers,
with a fagged brain, after a trying days work was a failure. The Sizelove
plan is a success and in every branch classes should be formed and analysis
of solutions taught by this method. It means not only progress but the only
way by which the plater can successfully hold his job in the modern plating
room. This plan will be the means of salvaging many men who will otherwise be
retired in the near future.
It is recognized that all the members
of the A. E. S. cannot attend the meetings of a branch society. There are many
in places where distance prevents attendance. These platers are just as anxious
to have the opportunity of learning how to control their solutions as their
more fortunately situated brother platers. Neither is it possible for the branch
societies to provide instruction for these platers. This has been recognized
by the writer of this article. He, therefore, obtained the privilege of offering
the facilities of the chemical laboratory under his supervision to all platers,
members of the A. E. S. who cannot attend classes in chemistry. It has been
found that if two full days are given to the study of each solution, under the
Sizelove plan, sufficient knowledge can be obtained so that with practice in
the plating room the plater can make the necessary analysis. The tools, the
chemicals and personal instruction are available to foreman platers without
any cost or obligation. This is done because it is realized that chemistry in
electroplating is not coming, but is here, and that the plater who does not
know how to control his solutions in a few years will be the old timer
and if he loses his job it will be difficult to get another, the other plater
applying will know what he should knowcontrol of solutions. The Sizelove
plan opens the way to better plating and will make platers more successfuland
you to be or not to be, that is the question. This is your
opportunity. What is your answer?
David Ayres, Toronto Branch
Mr. President and fellow members,
A. E. P. S., we will here try to give a few words of advice on the care of plating
dynamos. In the first place we must consider that the dynamos in the plating
room have the same relation to the rest of the equipment that the locomotive
has to the express train. It is our source of power, and therefore should receive
our first consideration, it should rest on a solid foundation, and as far as
possible be free from vibration, and be run at the regular speed required by
the manufacturer. There are no doubt a large number of machines that are still
belt-driven, but we believe the motor-driven dynamos give by far the best results.
And now we come to the commutator
and brushes, which we might say can be regarded as sort of barometer at times,
what we mean by that is, suppose everything has been working smoothly in the
plant for some considerable time, and then the commutator of your dynamo develops
a bad case of sparking and you find the brushes are also cutting. We can be
sure there is something wrong and should immediately look for the cause of the
trouble. The first place to look is right at the commutator and brushes themselves,
are the brushes equally divided on the surface of the commutator, at times a
single brush will cause all the trouble by becoming loose, and consequently
is worn uneven and should be taken out and ground to the proper level, this
should be done on a fine emery wheel as near the diameter of the commutator
as possible, the contact surface of your brushes will then correspond very nearly
with the surface of commutator and will become adjusted more quickly, and your
commutator will acquire that glaze which every plater likes to see, and here
we might say something to lubrication. The usual plan is a piece of felt or
something similar, slightly saturated with oil, which is allowed to rest on
the lower set of brushes. The best lubricant that I have found is a mixture
of beeswax and plum bago about equal parts of each. Just melt the beeswax and
stir in the plum bago and let cool. I have found this very satisfactory, although
paraffin wax can be used when beeswax is not available. Occasionally the glaze
on the surface of commutator will become so pronounced that it becomes slightly
insulated, a drop of oil rubbed across the surface or a very fine piece of sandpaper
will do the trick.
Now we have done about all we can
do in regard to commutator and brushes, and they continue to spark and cut,
well must break for a short circuit or loose connection somewhere on tank rods,
or possibly a careless operator has allowed a piece of work to drop in one of
the tanks and leaves it there, it rest diagonally against the anodes, and when
the bath is again loaded, some of the parts come in contact with piece submerged,
the result is no end of trouble. I recall an occasion where this actually happened.
We believe it to be a good method to give the dynamos a little attention at
least once a day, be sure to oil regularly. In a number of plants the dynamos
are enclosed in a room by themselves and are not allowed to be exposed to the
moisture, and fumes from the plating room, or grit from the polishing room.
These are a few facts if followed,
we feel sure will give good results.
For the last few years cadmium plating
has had just recognition in the manufacturing world, on account of its rust
resisting qualities, its quickness of deposition and the fact that metal does
not have to be heavily plated in order to withstand the various changes in atmosphere
and climate to which so many articles are subjected, after they leave the factory.
When we consider that 1 mil. of cadmium plate equals 3 of zinc, it would seem
that cadmium plated parts would soon be in universal favor. The automobile industry
should be especially interested in this process inasmuch as exposed parts, such
as bumper bars, radiator shells, etc., have been the cause of considerable criticism
in the past, because of the failure of nickel plate to stand up
under ordinary conditions. Here we have a deposit which has proved its worth,
held its own under severe chemical tests and will long outlast other electro
deposits when exposed to atmospheric changes. Moreover a cadmium coating applied
to enameled articles that can be plated is a guarantee that these articles will
not rust, even should the enamel chip off. In a great majority of plating rooms
it has been customary to copper strike articles of steel and iron, previous
to nickel plating. A light coat of cadmium is far better as a rust preventive
and does not affect the nickel deposit or the appearance of the work after being
color buffed. Work that requires no previous preparation in the polishing room
will take a beautiful satin finish by being wire brushed after plating a coat
of clear lacquer, being applied to avoid marring the finish in handling.
This is sometimes used as a substitute for silver, the deception being barely
noticeable. Work that is cadmium plated by the barrel method, whether it be
composed of brass, copper, iron or steel, can be made to take a beautiful silvery
appearance by keeping an excess of sodium cyanide in the plating tank or by
being ball rolled after plating. It might be well to mention that cadmium plate
should not be used on cutlery and cooking utensils as the nature of the metal
does not harmonize with the human organism, and there is a remote possibility
that the use of cadmium on articles containing food in the home, might result
in rather unpleasant after effects.
To the person who undertakes cadmium
plating on a small scale, such as job shop work, the experiment would very likely
prove a costly one, unless this particular finish is definitely requested, but
to the manufacturer who has great quantities of work to be given a rust resisting
treatment, cadmium plate should make a strong appeal. There are several reasons,
first, it deposits very quickly, the time of deposition being three times at
least faster than nickel and twice as fast as electro galvanizing, there is
no peeling or blistering to contend with if work is properly cleaned, and if
by chance some pieces of work should happen to be rejected by the Inspection
Department, a few minutes in a hydro-chloric acid dip will remove the deposit,
and leave the surface smooth and bright so that these same articles can be replated
successfully without an extra buffing operation. Another advantage is that it
is easier to control this solution than some others, there being but two chemicals
to contend with. This should be a source of satisfaction to many platers who
have had their nickel solutions fail them when the Production Department insisted
that they couldnt wait another minute for the work.
Moreover, this deposit does not require
the amount of floor space for cleaning and plating tanks, etc., especially if
a moving cathode machine is used.
Carefully considering these facts
the logical conclusion is that even if the initial expense is greater as compared
with nickel and if the chemicals and anodes used in cadmium plating cost more
than a tank containing the same amount of nickel or zinc, the time saved, the
amount of surface covered and the added protection of cadmium clearly proves
its ultimate economy.
Regarding the process, cleaning is
the most important factor in cadmium plating. This is the secret of all finishing,
whether it be paint, lacquer, enameling or even soldering. Pickling or sandblasting
should be resorted to wherever there is a scaly surface, everything in the nature
of oil and grease should be removed in the usual way.
Anodes, too, are important in the
proper functioning of this process, three times the amount of anode surface
being neces-sary in the tank to the amount of material being plated. Fifteen
per cent of iron is required also which can very easily be made a part of the
anode by using strips of cold-rolled steel, 25 in. long, 1 in. wide and 1/4
in. thick, to which is fastened the cadmium disc, thus making a very substantial
anode for a tank of ordinary dimensions.
The cadmium solution is made as follows,
and is used with a current density of 30 amp. per square foot:
Water . . . . . . . . . . . . . .100
gallons
Sodium Cyanide. . . . 85 pounds
Cadmium Oxide . . . . 28 pounds
The solution can be used either cold
or hot. Where a cold solution is used there is a minimum of sodium carbonate
and hydrocyanic gas formed. When the solution is heated, the gas fume thrown
off becomes offensive and sometimes injurious to the operator and has to be
carried off with a blower. Rubber gloves are also necessary in handling this
solution as the mixture coming in contact with scratched or torn hands, causes
painful sores and blisters.
A steel tank is preferable to wood,
particularly in barrel plating as the solution very readily attacks anything
of a nonferrous nature in the mechanical equipment. Barrels used in cadmium
plating are short-lived especially when the solution is used hot.
Celluloid panels simply dissolve. Wood panels become so saturated that they
seem like pulp. The only material which seems to give any degree of satisfaction
is micarta and this must have a fabric base instead of paper. Micarta also has
its limitations unless the panels and framework are good and thick, with all
the perforations it is possible to get into the panels. The manufacturer of
plating supplies need not consider his work done until he can place in the plating
room a real honest-to-goodness plating barrel, which will stand the test that
the cadmium solution surely gives.
The time of plating depends upon
the density of the solution and the nature of the material to be plated. As
in other solutions, a large anode surface is necessary and more to be desired
than the frequent adding of metal in oxide form to the solution. This also reduces
the time of deposit so that a thickness of coating (.00025) should be deposited
on any article in from ten to twelve minutes in a still solution
and about thirty minutes in barrel plating.
After plating, all material should
be thoroughly rinsed in clean, cold, running water, then in hot water, to which
may be added a little whale oil soap, to prevent stains, (except when a subsequent
lacquer or japan finish is to be applied). Small parts can be dried in sawdust
or on a drying machine. Large pieces may be allowed to dry from the absorbed
heat.
Tests should be made frequently for
cyanide content, metal content and thickness of deposit, and are as follows:
Testing for Cyanide
Dissolve 14 grams of cadmium chloride in a little water. Add enough water to
make one quart of solution. Take 5 c.c. of plating solution and put in a four-ounce
bottle, fill the bottle one-third full with water and shake. Slowly add the
testing solution to the diluted-plating solution with a small graduate until
a distinct cloudiness appears and does not clear away. Each 5 c.c. of testing
solution which is necessary to add to obtain the cloudiness means that there
is one ounce of cyanide in the solution. The amount necessary to bring it up
to standard can then be calculated. The solution should contain between six
and seven ounces of cyanide to the gallon.
Testing for Metal
Dissolve 100 grams caustic soda in distilled water. Add 15 grams powdered sulphur
and boil for a few minutes. Filter off any undissolved sulphur. Next, dilute
the solution to one quart by using water. The solution is now ready for use.
To determine the metal content of plating solution, place 10 c.c. of the plating
solution in one of the graduates, add 25 c.c. of the testing solution, shake
thoroughly and let stand overnight. A yellow sediment will separate and settle
in bottom of graduate. Each 2 c.c. of sediment means that there is in the plating
solution one ounce of metal. As the solution should contain at least two
ounces of metal to the gallon, any deficiency can be calculated and the proper
amount of cadmium oxide added.
Testing for Thickness of Deposit
To each 100 c.c. of hydrochloric acid (C. P. or commercial grade) which has
been diluted to reach 1.135 specific gravity (17 degrees BE) add 5 c.c. of liquid
butter of antimony. The butter of antimony must have a specific gravity of 1.6.
The stripping solution is now ready. Place representative samples from each
run in plating tank into the stripping or testing solution. As long as any cadmium
remains on the article, a distinct bubbling will be seen. When the cadmium is
gone, the bubbling ceases, which is to be taken as the finishing time. To be
a satisfactory coating, the article being tested must bubble for forty seconds,
which is equal to a thickness of coating of .00025. Not more than four samples
should be dipped in the same stripping solution.
Cadmium plate is not as hard a deposit
as nickel and will mar and scratch as easily as silver, it has moreover a tendency
to stain easily so that the greatest care should be taken in rinsing after coming
from the plating bath.
WESTINGHOUSE ELEC. &
MFG. CO., East Springfield Works, Mass.
The value of any publication depends
upon whether the matter presented is of a nature that will gain the goal sought.
The Monthly Reviewthe organ of the A. E. S., an educative organizationshould
contain that which will add to the knowledge of the members. There should not
only be the reports of the meetings of the Branch Societies, which is of general
interest, but original papers on subjects that represent the best thought of
the day on new or improved practice. There should also be the news
of the plating industry throughout the world. The word Review implies
that. A reading of the matter presented would seem to indicate that there has
been a Monthly rather than a Monthly Review.
In development work, in research work, in fact in the everyday shop work, it
is of much importance to know what has been done or what the other fellow thought
could be done. Valuable time and effort is spent in doing work that has been
done and in a great many cases the data obtained has been published. There are
inquisitive platers all over the world experimenting and collecting data just
the same as many A. E. S. members. They are enthused with the self-same ambition
to tell their fellow platers what they have done. There is the chemist also
who, being interested in electricity and metallurgy, experiments with the electro-deposition
of metals. His training enables him to observe and record things that so often
pass unnoticed by those who daily come in contact with similar conditions. Such
investigators take pride in contributing their results to the good work of advancing
methods of operation in electroplating.
In nearly all fields of endeavor
there are publications devoted to collecting and making known all the available
work done along a special line. There is one notable exception, and that is,
the direct field of electroplating.
Nothing could be more educative than
to have the opportunity of reading a short review of the work done, the patents
issued and the books published. Part of this is in a measure covered but more
attention is given to original articles, which so often can be read in three
or four different publications. This limits the amount of knowledge available
to all the members of the society as it is only a few who have the privilege
or opportunity of having access to all publications. To subscribe to all would
be beyond the means of many.
This is a situation that should be
met and corrected by the Monthly Review. In an endeavor to do so, a Publication
Committee was appointed at the last convention. Plans are being formulated whereby
all the available writings on electroplating, in a review form, will be placed
before not only the platers who can attend branch meeting regularly but also
be given to those less fortunately situated but who are just as thirsty for
knowledge and just as anxious to be a well informed progressive plater.
This cannot be accomplished at once.
It will require considerable work and, most of all, co-operation on the part
of ;those who are able to assist. The start has been made and eventually the
A. E. S. will have in reality a Monthly Review.
Publishing Committee, A.
E. S.
Q.--Are iron hooks or anything
in iron detrimental to a silver solution?
A.--The members did not think
so.
Q.--What is good formula for
a cyanide copper solution?
A.--3 oz. copper cyanide,
3 1/4 oz. sodium cyanide, 1 oz. sodium carbonate. Per gallon. Heat to Fahrenheit
120 when working.
Q.--What is good for taking
up excess acid in nickel plating solution?
A.--Nickel carbonate if metal
content is low; magnesium carbonate if metal content is sufficient.
Henry Ford, in his concluding chapter
of The Great Today, the Greater Tomorrow running in Boston Globe
and New York American, says: Morality is part of good management. The
social effect of this morality finds expression in devoting business to the
service of the whole people instead of to the service of the few. The spirit
of service is just a knowledge that no man can survive, no industry can survive,
no government can survive, no system of civilization can survive, which does
not continually give service to the greatest possible manner. There is no way
out from poverty except through work. The world has tried everything but work,
and the hardest of all work must come in the management. The majority of labor
troubles are caused by managers who have no first hand knowledge of labor.